Hides may be received
in any of following conditions: fresh, green-salted, sun-dried or
dry salted. Fresh hides are not common. The hides from the slaughterhouses
are salted and await shipment to the tanneries. Hides form the foreign
countries are likely to be dried, or salted and dried; these are
stiff and hard, and require special treatment.
Washing:
All hides are first washed to remove blood, dirt, and free salt.
This may be done in the vats or "wash wheel", a large
drum mounted on trunnions, which receives the hides and wash water
and tumbles them by rotation on it's axis. These drums are characteristic
feature of the tannery and are used in many of it's operations.
Soaking:
For the purpose of removing salt and to soften hides, they
are next suspended in the vats of cold water, with frequent changing
of the water in the vat or countercurrent movement of hides from
vat to vat. The soda ash, detergents and bacteria are mixed in water
for better results. The duration of soaking depends on the condition
of the hides. The usual duration is 12-14 hrs.
The combined waste from the washing and soaking is called "soaks".
It contains dirt, dung, blood, some hair, and salt. They are dark,
olive-green in colour and highly putrescible. The discharge is intermittent.
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Liming:
To swell the skins and so that the tanning agents may penetrate
the skin the liming is done. The hides are immersed in the solution
of lime and sodium sulfate for about 5-10 days. They are mixed in
the proportion of 3.5-4.5% of the total weight of the hides. Out
of this 2-2.5% is lime. The liming process may also serve to remove
the grease from the hides. The lime waste is one of the heaviest
of the waste in the tanning process and accounts for the more conspicuous
characteristics of the tannery waste.
Unhairing:
Unhairing is accomplished by the machines in which knife-bearing
rollers sweep over the skin and remove the loosened hair and epidermis
which are flushed off in the stream of water. The hair is separated
and washed in clean water. The waste from this process contains
fine hair which escape the screen, together with the particles of
epidermis and lime. Discharge is continuous.
The unhaired are then given vigorous washing in clean water to remove
lime. This operation may be conducted in drums or in vats supplied
with the steady flow of clean water. The waste from the washing
operation is relatively large in volume, but of low strength.
Fleshing:
It is the next process. This is the removal of the muscle and fatty
tissues adhering to the underside of the hide. In the modern tanning
process the fleshing is done on the machine which brings the revolving
knives against the hides while the stream of the water carries away
the particles removed.
Bating:
Then comes this process whose purpose is to remove the lime absorbed
by the hides, and hydrolysis of some protien which are not required
in the fine leather. It also restores the thickness of hides.
In modern tanning the bate is the solution of the proteolytic enzyme,
such as pancreatic or trypsin, plus the ammonium salt such as ammonium
sulfate and ammonium bi-sulfate. The former removes the unwanted
proteins such as absorbed lime. As a waste producer, the process
is of little importance.
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Pickling:
It is an important step in the preparation of the leather. It consists
of soaking the skins in the solution of the sulphuric acid and the
sodium chloride. The purpose of the pickling is to lower the pH
level so that the skins can be chrome tanned. After pickling the
skins can be preserved for long times before they can be tanned.
The process is performed in the wash wheels or vats, where the skins
remain for the 10-16 hrs. the pickling liquor can be brought back
to strength and thus can be re-used over a considerable period and
therefore discharged only occasionally.
Tanning:
After pickling the skins are tanned. The skins are charged into
the drums containing a solution of basic chromium sulfate. Salts
like sodium chloride or sulfate is also added in the solution to
promote the penetration of the chromium salt into the skin. Tanning
is completed in the rotating drum in the few hours. If vats are
used then it might take several days. Towards the end of the process
the soda ash is added to promote the combination of the tanning
agent with the skin substance.
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